{
  "schema_version": "foamforge-particles-v2",
  "access_date": "2026-10-10",
  "pressure_conversion": {
    "psi_to_mpa": 0.006894757293168
  },
  "scope": "Supplier references and explicit links to the unchanged legacy catalogue. Reference inclusion is not model or hydrostatic validation.",
  "sources": {
    "3m_s15": {
      "url": "https://www.3m.com/3M/en_US/p/dc/v000191956/",
      "title": "3M Glass Bubbles S15, 265lb",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_current_page",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "3m_compounding": {
      "url": "https://multimedia.3m.com/mws/media/1233016O/3m-glass-bubbles-compounding-and-injection-molding-guidelines.pdf",
      "title": "3M Glass Bubbles Compounding and Injection Molding Guidelines",
      "source_date": "2021-05",
      "access_date": "2026-10-10",
      "type": "manufacturer_pdf",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "059eaf8babee79945abfcbef189f237ac8f1396e19d964da7b0032a7f23995ff",
      "review_method": "PDF text and rendered table/header inspection",
      "source_date_basis": "Footer on p.7: issued 5/21"
    },
    "3m_im16k_method": {
      "url": "https://multimedia.3m.com/mws/media/868489O/3m-glass-bubbles-im16k-for-reinforced-thermoplastics.pdf",
      "title": "3M Glass Bubbles iM16K for Reinforced Thermoplastics, Table1",
      "source_date": "2016-10",
      "access_date": "2026-10-10",
      "type": "manufacturer_technical_paper",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "46424f06d6d10979e1d70ea748a34aea489441a721f7787ee68514c6b6563b6a",
      "review_method": "PDF text and rendered table/header inspection",
      "source_date_basis": "Footer on p.5: issued 10/16",
      "limitations": "Table 1 reports iM16K particle properties; composite processing results in the paper are not validations of FoamForge predictions."
    },
    "3m_overview": {
      "url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "title": "3M Glass Bubbles Overview, table p11",
      "source_date": "2019-09",
      "source_date_basis": "Footer: issued 9/19, Rev B",
      "access_date": "2026-10-10",
      "type": "manufacturer_pdf",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "e2c850421327c98cb9d5231534fba2229d7100b3241296cdcedeafa89956a64a",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "3m_uk_ks": {
      "url": "https://multimedia.3m.com/mws/media/619093O/3m-glass-bubbles-types-k-and-s-uk-data-sheet.ai?fn=K_S_Bubbles_UKdat.pdf",
      "title": "3M Glass Bubbles K Series / S Series Product Information",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_archival_pdf",
      "limitations": "Official URL serves a PDF with a postscript content type. Downloaded and visually reviewed on 2026-10-10. No issue date found; retains different S15 survival, S60/iM30K pressures and S38HS/S60HS/iM30K sizes as separate observations.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "b089c9261daf628a0c6b56cb673291c4fa96d1fc61367cc59a49a7881002ef73",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "3m_s60": {
      "url": "https://www.3m.com/3M/en_US/p/d/b40064607/",
      "title": "3M Glass Bubbles S60",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_current_page",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "3m_h50_rds": {
      "url": "https://multimedia.3m.com/mws/mediawebserver?mwsId=SSSSSu9n_zu8l00x4x_ZNxtGOv70k17zHvu9lxtD7xt1evSSSSSS-",
      "title": "3M Glass Bubbles Types H, H20/1000, H50/10000 Regulatory Data Sheet",
      "source_date": "2024-01-31",
      "access_date": "2026-10-10",
      "type": "manufacturer_regulatory_sheet",
      "limitations": "Verifies named H50/10000 family, not exact identity of bare legacy H50 in repo; no mechanical specification taken from RDS.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "cd2585165df7f229f9d0acea47c050429ff444a459c89144e0f08df34ea2cb25",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "ecco_web": {
      "url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "title": "Trelleborg Eccospheres typical properties",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_current_page",
      "limitations": "Undated table; density described as average density \u00b10.02, no measurement method; psi footnote not displayed in parsed webpage.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "ecco_2017": {
      "url": "https://www.trelleborg.com/applied-technologies/~/media/applied-technologies/en/resources/feb-2017-updates/trelleborg-datasheet-eccospheres-02.pdf",
      "title": "Trelleborg Eccospheres typical properties and ASTM D3102-78 footnote",
      "source_date": null,
      "source_date_basis": "URL path references February 2017, not proof of issue date",
      "access_date": "2026-10-10",
      "type": "manufacturer_archival_pdf",
      "limitations": "Historic sheet establishes 80% survival criterion for listed grades; vendor should confirm current specification.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "d56e5e30c75fc71ace1a04246cd7e660322beaa426e76dc4241629bd8862066c",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "ecco_electronic": {
      "url": "https://www.trelleborg.com/applied-technologies/-/media/applied-technologies/en/product-sheets/hollow-shell-fillers/trelleborg-eccospheres.pdf?rev=a8c27b251fb04003a5038e5d1ccfd5c1",
      "title": "Eccospheres for Electronic Applications, p2",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_pdf",
      "limitations": "PDF p.2 visibly prints SI200 nominal density as 130 kg/m3 versus 200 kg/m3 on the product page; SID160z differs from website SID-106Z. SID311z / FTD311z is a combined row; do not infer grade interchangeability. No pressure table.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "460679226c990997f5455ab7b13a5fac022d4db9ddd8917c8b18c3c03490f9d1",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "potters_web": {
      "url": "https://www.pottersindustries.com/micro-glass-beads/",
      "title": "Potters micro glass beads",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_current_page",
      "limitations": "Family-level properties, no current grade table or detailed pressure method.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "potters_japan": {
      "url": "https://www.pqj.co.jp/en/%E4%B8%AD%E7%A9%BA%E3%82%AC%E3%83%A9%E3%82%B9%E3%83%93%E3%83%BC%E3%82%BA",
      "title": "Potters-Ballotini Japan hollow glass spheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_current_page",
      "limitations": "Explicitly names Sphericel110P8, no quantitative TDS. Corporate page confirms shareholder Potters International Holdings.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "potters_sphericel_2012": {
      "url": "https://www.thecarycompany.com/media/pdf/adobe/Sphericel-TDS.pdf",
      "title": "Potters Sphericel General2012 manufacturer-authored sheet hosted by distributor",
      "source_date": "2012",
      "access_date": "2026-10-10",
      "type": "manufacturer_authored_distributor_hosted_archival_pdf",
      "limitations": "Historical data only. Current values/grade availability not established. Distinct2011sheet omits survival footnote; use this2012version.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "173f8e16d994c217d7c1e20d6e3ed69ce412968bf05a2964eb66b4c12f51a267",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "potters_qcel_archival": {
      "url": "https://www.thecarycompany.com/media/pdf/adobe/potters/q-cel-300-6014-6019-6028.pdf",
      "title": "Potters Q-CEL300/6014/6019/6028 historical sheet",
      "source_date": null,
      "access_date": "2026-10-10",
      "type": "manufacturer_authored_distributor_hosted_archival_pdf",
      "limitations": "Effective liquid-displacement density is not labelled true density. Not sufficient for current-grade verification.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "content_sha256": "cf8403488d93655aae947f5a76f80e3c56d2a0a849b9412a51214f8453368439",
      "review_method": "PDF text and rendered table/header inspection"
    },
    "local_psp": {
      "url": null,
      "title": "FoamGPT stored literature extraction",
      "path": "data/foamgpt_psp.csv",
      "access_date": "2026-10-10",
      "source_date": null,
      "type": "local_extracted_literature",
      "limitations": "Source labels and OCR are not confirmed supplier specifications; matching rows may not be independent.",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "local_reference_reviewed",
      "review_method": "Stored extraction link review; original papers not revalidated",
      "content_sha256": "134f0acd9948897c4c656bcaf54460278ae01040fdc3a0337d198f57a1371689"
    },
    "3m_s60_tds": {
      "url": "https://multimedia.3m.com/mws/media/184505O/3m-tm-glass-bubbles-s60.pdf?fn=gbs60.pdf",
      "title": "3M Glass Bubbles S60, typical physical properties",
      "source_date": "2017-07",
      "source_date_basis": "Footer on p.2: issued 7/17, Rev. B",
      "type": "manufacturer_pdf",
      "limitations": "Linked from the current S60 product page, but issued in 2017; typical properties, not specification values.",
      "access_date": "2026-10-10",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "PDF text and rendered table inspection",
      "content_sha256": "079781c7c9e0a6e599af562d88582697a48bd632339a8753c29c4d5fb1225784"
    },
    "3m_buoyancy_2020": {
      "url": "https://multimedia.3m.com/mws/media/1965520O/14473-glass-bubbles-insulation-and-buoyancy-sales-card-2020.pdf",
      "title": "3M Glass Bubbles for Buoyancy and Thermal Insulation",
      "source_date": "2020-09",
      "source_date_basis": "Footer on p.2: issued 9/20",
      "type": "manufacturer_pdf",
      "limitations": "Particle values corroborate selected overview rows. Foam densities and thermal conductivities in this sheet are calculated under stated assumptions, not measured qualified products.",
      "access_date": "2026-10-10",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "PDF text and rendered table inspection",
      "content_sha256": "64791c96e7e2f72008f150f7f7d160e9a637580b6fdb78c4db79878ddc58d542"
    },
    "3m_k1": {
      "url": "https://www.3m.com/3M/en_US/p/dc/v000194027/",
      "title": "3M Glass Bubbles K1, 210 lb (95 kg)",
      "source_date": null,
      "type": "manufacturer_current_page",
      "limitations": "Current public page corroborates particle density and pressure/survival; it is not a lot certificate or a foam depth qualification.",
      "access_date": "2026-10-10",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "retrieved_and_reviewed",
      "review_method": "Manufacturer webpage content inspection"
    },
    "local_legacy_particles": {
      "url": null,
      "title": "Superseded FoamForge particle reference export, before 2026-10-10 correction",
      "source_date": null,
      "type": "superseded_local_reference",
      "limitations": "Source hash identifies the old export at the recorded Git revision. Values are retained as historical observations; the current compatibility export is generated from this registry and is not a model input.",
      "access_date": "2026-10-10",
      "reviewed_at": "2026-10-10",
      "retrieval_status": "local_reference_reviewed",
      "review_method": "Local legacy data comparison",
      "content_sha256": "a8f4b1d6371ee606a854e8bfba6d1c5e581fed41009f0389d2ac824fcc9d6aca",
      "historical_path": "website/public/data/microballoons_3m.json",
      "git_revision": "51f1701078a9d2ed55fccda24bcf65b528f41dff"
    }
  },
  "records": [
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K1",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.125,
      "reported_density_g_cm3": 0.125,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 65,
      "pressure_psi": 250,
      "pressure_mpa": 1.723689,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020",
        "3m_k1"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.125,
          "density_min_g_cm3": 0.1,
          "density_max_g_cm3": 0.14,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 65,
          "d10_um": 30,
          "d90_um": 115,
          "pressure_psi": 250,
          "pressure_mpa": 1.723689,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k1",
      "model_status": "legacy_catalogue",
      "model_grade_id": "K1",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K1 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K15",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.15,
      "reported_density_g_cm3": 0.15,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 60,
      "pressure_psi": 300,
      "pressure_mpa": 2.068427,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.15,
          "density_min_g_cm3": 0.13,
          "density_max_g_cm3": 0.17,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 60,
          "d10_um": 30,
          "d90_um": 105,
          "pressure_psi": 300,
          "pressure_mpa": 2.068427,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k15",
      "model_status": "legacy_catalogue",
      "model_grade_id": "K15",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K15 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K20",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.2,
      "reported_density_g_cm3": 0.2,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 60,
      "pressure_psi": 500,
      "pressure_mpa": 3.447379,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.2,
          "density_min_g_cm3": 0.18,
          "density_max_g_cm3": 0.22,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 60,
          "d10_um": 30,
          "d90_um": 90,
          "pressure_psi": 500,
          "pressure_mpa": 3.447379,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k20",
      "model_status": "legacy_catalogue",
      "model_grade_id": "K20",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K25",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.25,
      "reported_density_g_cm3": 0.25,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 55,
      "pressure_psi": 750,
      "pressure_mpa": 5.171068,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.25,
          "density_min_g_cm3": 0.23,
          "density_max_g_cm3": 0.27,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 55,
          "d10_um": 25,
          "d90_um": 90,
          "pressure_psi": 750,
          "pressure_mpa": 5.171068,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k25",
      "model_status": "legacy_catalogue",
      "model_grade_id": "K25",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K25 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K37",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.37,
      "reported_density_g_cm3": 0.37,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 45,
      "pressure_psi": 3000,
      "pressure_mpa": 20.684272,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.37,
          "density_min_g_cm3": 0.34,
          "density_max_g_cm3": 0.4,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 45,
          "d10_um": 20,
          "d90_um": 80,
          "pressure_psi": 3000,
          "pressure_mpa": 20.684272,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k37",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K37 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K46",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.46,
      "reported_density_g_cm3": 0.46,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 6000,
      "pressure_mpa": 41.368544,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020",
        "3m_compounding"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.46,
          "density_min_g_cm3": 0.43,
          "density_max_g_cm3": 0.49,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 40,
          "d10_um": 15,
          "d90_um": 70,
          "pressure_psi": 6000,
          "pressure_mpa": 41.368544,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k46",
      "model_status": "legacy_catalogue",
      "model_grade_id": "K46",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K46 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S15",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.15,
      "reported_density_g_cm3": 0.15,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 55,
      "pressure_psi": 300,
      "pressure_mpa": 2.068427,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 85,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_s15",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "Official source conflict: overview gives 85% minimum; undated UK sheet gives 80% minimum / 90% target at 300 psi."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.15,
          "density_min_g_cm3": 0.13,
          "density_max_g_cm3": 0.17,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 55,
          "d10_um": 25,
          "d90_um": 90,
          "pressure_psi": 300,
          "pressure_mpa": 2.068427,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s15",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S15 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S22",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.22,
      "reported_density_g_cm3": 0.22,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 35,
      "pressure_psi": 400,
      "pressure_mpa": 2.757903,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.22,
          "density_min_g_cm3": 0.19,
          "density_max_g_cm3": 0.25,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 35,
          "d10_um": 20,
          "d90_um": 65,
          "pressure_psi": 400,
          "pressure_mpa": 2.757903,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s22",
      "model_status": "legacy_catalogue",
      "model_grade_id": "S22",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S22 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S32",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.32,
      "reported_density_g_cm3": 0.32,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 2000,
      "pressure_mpa": 13.789515,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.32,
          "density_min_g_cm3": 0.29,
          "density_max_g_cm3": 0.35,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 40,
          "d10_um": 20,
          "d90_um": 70,
          "pressure_psi": 2000,
          "pressure_mpa": 13.789515,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s32",
      "model_status": "legacy_catalogue",
      "model_grade_id": "S32",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S35",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.35,
      "reported_density_g_cm3": 0.35,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 3000,
      "pressure_mpa": 20.684272,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.35,
          "density_min_g_cm3": 0.32,
          "density_max_g_cm3": 0.38,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 40,
          "d10_um": 20,
          "d90_um": 65,
          "pressure_psi": 3000,
          "pressure_mpa": 20.684272,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s35",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S35 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S38",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.38,
      "reported_density_g_cm3": 0.38,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 4000,
      "pressure_mpa": 27.579029,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.38,
          "density_min_g_cm3": 0.35,
          "density_max_g_cm3": 0.41,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 40,
          "d10_um": 15,
          "d90_um": 75,
          "pressure_psi": 4000,
          "pressure_mpa": 27.579029,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s38",
      "model_status": "legacy_catalogue",
      "model_grade_id": "S38",
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S38HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.38,
      "reported_density_g_cm3": 0.38,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 5500,
      "pressure_mpa": 37.921165,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_buoyancy_2020",
        "3m_compounding"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "Undated UK sheet gives D50 by volume 44 um under QCM 193.0; 2019 overview gives 40 um under QCM 193.2. Distinct source versions/methods retained; no interchangeable size assumed."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.38,
          "density_min_g_cm3": 0.35,
          "density_max_g_cm3": 0.41,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 44,
          "d10_um": 19,
          "d90_um": 70,
          "pressure_psi": 5500,
          "pressure_mpa": 37.921165,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s38hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S60",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.6,
      "reported_density_g_cm3": 0.6,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 30,
      "pressure_psi": 6000,
      "pressure_mpa": 41.368544,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "90% survival by volume (2017 S60 datasheet); overview gives minimum fractional survival",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_s60",
        "3m_uk_ks",
        "3m_compounding",
        "local_legacy_particles",
        "3m_s60_tds"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "Current product page corroborates 6,000 psi / 90% survival. Legacy 10,000 psi / 80% basis must be retained as separate versioned observation, not mixed."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.6,
          "density_min_g_cm3": 0.57,
          "density_max_g_cm3": 0.63,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 30,
          "d10_um": 15,
          "d90_um": 55,
          "pressure_psi": 10000,
          "pressure_mpa": 68.947573,
          "minimum_survival_percent": 80,
          "target_survival_percent": 90
        },
        {
          "pressure_mpa": 68.9,
          "source_id": "local_legacy_particles",
          "observation_status": "superseded_local_reference",
          "locator": "S60 entry",
          "access_date": "2026-10-10",
          "source_date": null
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s60",
      "model_status": "legacy_catalogue",
      "model_grade_id": "S60",
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_s60_tds",
            "3m_overview"
          ],
          "locator": "S60 datasheet p.1 typical properties; overview p.11"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S60HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.6,
      "reported_density_g_cm3": 0.6,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 30,
      "pressure_psi": 18000,
      "pressure_mpa": 124.105631,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_uk_ks",
        "3m_compounding"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "Undated UK sheet gives D50 by volume 29 um under QCM 193.0; 2019 overview gives 30 um under QCM 193.2. Distinct source versions/methods retained; no interchangeable size assumed."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.6,
          "density_min_g_cm3": 0.57,
          "density_max_g_cm3": 0.63,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 29,
          "d10_um": 12,
          "d90_um": 48,
          "pressure_psi": 18000,
          "pressure_mpa": 124.105631,
          "minimum_survival_percent": 90,
          "target_survival_percent": 90
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s60hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S60HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "iM16K",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.46,
      "reported_density_g_cm3": 0.46,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": 0.03,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 20,
      "pressure_psi": 16000,
      "pressure_mpa": 110.316117,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": "3M QCM 14.1.83M (2016 technical paper, Table 1)",
      "source_ids": [
        "3m_overview",
        "3m_im16k_method",
        "3m_buoyancy_2020",
        "3m_compounding"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Pressure method and density tolerance come from the 2016 iM16K technical paper; size D50 weighting/method comes from the 2019 overview. These sources are not a current lot certificate."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:im16k",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM16K row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        },
        "test_method": {
          "source_ids": [
            "3m_im16k_method"
          ],
          "locator": "p.1, Table 1; paper issued 2016-10"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "3m_im16k_method"
          ],
          "locator": "p.1, Table 1; paper issued 2016-10"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "iM30K",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.6,
      "reported_density_g_cm3": 0.6,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 18,
      "pressure_psi": 27000,
      "pressure_mpa": 186.158447,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_compounding",
        "3m_uk_ks",
        "local_legacy_particles"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "2019 overview 27,000 psi conflicts with undated UK 28,000 psi / local 193.1 MPa; use versioned observations.",
        "Undated UK sheet gives D50 by volume 15.3 um under QCM 193.0; 2019 overview gives 18 um under QCM 193.2. Distinct source versions/methods retained; no interchangeable size assumed."
      ],
      "alternate_observations": [
        {
          "source_id": "3m_uk_ks",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "PDF p.1 pressure/density tables; p.2 size table",
          "observation_status": "undated_supplier_version",
          "true_density_g_cm3": 0.6,
          "density_min_g_cm3": 0.57,
          "density_max_g_cm3": 0.63,
          "particle_size_statistic": "D50 by volume (3M QCM 193.0)",
          "particle_size_um": 15.3,
          "d10_um": 8.6,
          "d90_um": 23.6,
          "pressure_psi": 28000,
          "pressure_mpa": 193.053204,
          "minimum_survival_percent": 90,
          "target_survival_percent": 90
        },
        {
          "pressure_mpa": 193.1,
          "source_id": "local_legacy_particles",
          "observation_status": "superseded_local_reference",
          "locator": "iM30K entry",
          "access_date": "2026-10-10",
          "source_date": null
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:im30k",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, iM30K row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "H50/10,000 EPX",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.5,
      "reported_density_g_cm3": 0.5,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 35,
      "pressure_psi": 10000,
      "pressure_mpa": 68.947573,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_h50_rds"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure.",
        "Full grade suffix matters; mapping legacy bareH50 to this EPX surface-treated grade is unverified."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:h50-10-000-epx",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, H50/10,000 EPX row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "H50",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "3m_h50_rds"
      ],
      "source_url": "https://multimedia.3m.com/mws/mediawebserver?mwsId=SSSSSu9n_zu8l00x4x_ZNxtGOv70k17zHvu9lxtD7xt1evSSSSSS-",
      "source_date": "2024-01-31",
      "access_date": "2026-10-10",
      "verification_status": "legacy_identity_unresolved",
      "uncertainties": [
        "Local model uses shorthand H50; current located quantitative overview names H50/10,000 EPX. Do not silently alias or substitute. Obtain original model/literature grade specification."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:h50",
      "model_status": "legacy_catalogue",
      "model_grade_id": "H50",
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "unresolved_identity"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K11",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.11,
      "reported_density_g_cm3": 0.11,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 65,
      "pressure_psi": 200,
      "pressure_mpa": 1.378951,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k11",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K11 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K20HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.2,
      "reported_density_g_cm3": 0.2,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 60,
      "pressure_psi": 750,
      "pressure_mpa": 5.171068,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k20hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K20HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S32LD",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.29,
      "reported_density_g_cm3": 0.29,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 40,
      "pressure_psi": 1500,
      "pressure_mpa": 10.342136,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 80,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s32ld",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32LD row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "XLD3000",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.23,
      "reported_density_g_cm3": 0.23,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 30,
      "pressure_psi": 3000,
      "pressure_mpa": 20.684272,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:xld3000",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, XLD3000 row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S28HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.28,
      "reported_density_g_cm3": 0.28,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 30,
      "pressure_psi": 3000,
      "pressure_mpa": 20.684272,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s28hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S28HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S38XHS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.38,
      "reported_density_g_cm3": 0.38,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 35,
      "pressure_psi": 5500,
      "pressure_mpa": 37.921165,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s38xhs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S38XHS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S32HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.32,
      "reported_density_g_cm3": 0.32,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 25,
      "pressure_psi": 6000,
      "pressure_mpa": 41.368544,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s32hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S32HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "K42HS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.42,
      "reported_density_g_cm3": 0.42,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 22,
      "pressure_psi": 7500,
      "pressure_mpa": 51.71068,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_compounding"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:k42hs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, K42HS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "3M",
      "family": "Glass Bubbles",
      "grade": "S42XHS",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": 0.42,
      "reported_density_g_cm3": 0.42,
      "density_basis": "True density; table method not stated",
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": "D50 by volume (3M QCM193.2)",
      "particle_size_um": 22,
      "pressure_psi": 8000,
      "pressure_mpa": 55.158058,
      "pressure_property": "particle crush test pressure",
      "survival_percent": 90,
      "survival_basis": "Minimum fractional survival in source table",
      "test_method": null,
      "source_ids": [
        "3m_overview",
        "3m_buoyancy_2020"
      ],
      "source_url": "https://multimedia.3m.com/mws/media/1028330O/3m-glass-bubbles-overview.pdf?fn=3M_Glass_Bubbles_Overview_0919_web_US_R6.pdf",
      "source_date": "2019-09",
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "2019 supplier overview remains publicly hosted; obtain current lot/specification before procurement.",
        "Typical values, not specification values.",
        "Crush test method is not specified in this table; QCM193.2 footnote applies to size, not pressure."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "3m:s42xhs",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "true_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "reported_density_g_cm3": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "density_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "particle_size_statistic": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "particle_size_um": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "pressure_psi": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "pressure_property": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "survival_percent": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "survival_basis": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "p.11, S42XHS row and table headings/footnote"
        },
        "pressure_mpa": {
          "source_ids": [
            "3m_overview"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "historical_supplier_reference"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "FTD-200",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.2,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 65,
      "pressure_psi": 750,
      "pressure_mpa": 5.171068,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:ftd-200",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-200 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "FTD-250",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.25,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 55,
      "pressure_psi": 1200,
      "pressure_mpa": 8.273709,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:ftd-250",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, FTD-250 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, FTD-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SI-100",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.1,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 65,
      "pressure_psi": 250,
      "pressure_mpa": 1.723689,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:si-100",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-100 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-100 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-100 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-100 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SI-160",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.2,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 62,
      "pressure_psi": 400,
      "pressure_mpa": 2.757903,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "supplier_value_conflict",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method.",
        "Current webpage 0.20 g/cc versus archival sheet 0.16 g/cc. Published web value preserved; no silent correction."
      ],
      "alternate_observations": [
        {
          "source_id": "ecco_2017",
          "reported_density_g_cm3": 0.16,
          "access_date": "2026-10-10",
          "source_date": null
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:si-160",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-160 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-160 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-160 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-160 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SI-200",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.2,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 60,
      "pressure_psi": 800,
      "pressure_mpa": 5.515806,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017",
        "ecco_electronic"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "supplier_value_conflict",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method.",
        "Electronics PDF p.2 lists SI200 nominal 130 kg/m3 versus 200 kg/m3 on webpage and archival sheet; flag vendor-document inconsistency."
      ],
      "alternate_observations": [
        {
          "source_id": "ecco_electronic",
          "reported_density_kg_m3": 130,
          "access_date": "2026-10-10",
          "source_date": null
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:si-200",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-200 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-200 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SI-250",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.25,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 60,
      "pressure_psi": 1800,
      "pressure_mpa": 12.410563,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:si-250",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SI-250 row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SI-250 row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-106Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.16,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 60,
      "pressure_psi": 600,
      "pressure_mpa": 4.136854,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "ecco_web",
        "ecco_2017",
        "ecco_electronic"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "supplier_grade_identity_conflict",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method.",
        "Web grade SID-106Z conflicts with SID-160Z/SID160z in official PDFs. Do not auto-alias or assign historical pressure method across unresolved identity."
      ],
      "alternate_observations": [
        {
          "source_id": "ecco_2017",
          "grade": "SID-160Z",
          "reported_density_g_cm3": 0.16,
          "particle_size_um": 60,
          "pressure_psi": 600,
          "survival_percent": 80,
          "test_method": "ASTM D3102-78",
          "access_date": "2026-10-10",
          "source_date": null
        },
        {
          "source_id": "ecco_electronic",
          "grade": "SID160z",
          "reported_density_kg_m3": 160,
          "access_date": "2026-10-10",
          "source_date": null
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-106z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-106Z row"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-200Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.2,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 53,
      "pressure_psi": 1000,
      "pressure_mpa": 6.894757,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-200z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-200Z row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-200Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-200Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-200Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-230Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.23,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 52,
      "pressure_psi": 2100,
      "pressure_mpa": 14.47899,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-230z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-230Z row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-230Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-230Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-230Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-270Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.27,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 50,
      "pressure_psi": 5000,
      "pressure_mpa": 34.473786,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-270z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-270Z row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-270Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-270Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-270Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-311Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.31,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 45,
      "pressure_psi": 6000,
      "pressure_mpa": 41.368544,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017",
        "ecco_electronic"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [
        {
          "source_id": "ecco_electronic",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "p.2 specified values table",
          "grade": "SID311z / FTD311z",
          "reported_density_kg_m3": 311,
          "particle_size_um": 45,
          "observation_status": "combined_grade_label",
          "note": "Webpage rounds density to 0.31 g/cc with +/-0.02 range. Electronics sheet lists 311 kg/m3 on a combined label; no grade equivalence inferred."
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-311z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-311Z row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-311Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-311Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-311Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Trelleborg Applied Technologies",
      "family": "Eccospheres",
      "grade": "SID-350Z",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": 0.35,
      "density_basis": "Average density range per webpage; true-density terminology/method not specified",
      "density_tolerance_g_cm3": 0.02,
      "particle_size_statistic": "mean (weighting not specified)",
      "particle_size_um": 45,
      "pressure_psi": 6500,
      "pressure_mpa": 44.815922,
      "pressure_property": "particle isostatic collapse test pressure",
      "survival_percent": 80,
      "survival_basis": "80% survival per archival manufacturer sheet; current web footnote omitted",
      "test_method": "ASTM D3102-78 (archival sheet)",
      "source_ids": [
        "ecco_web",
        "ecco_2017"
      ],
      "source_url": "https://www.trelleborg.com/en/applied-technologies/products-and-solutions/hollow-shell-fillers/eccospheres",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "manufacturer_reference_not_prediction_validation",
      "uncertainties": [
        "Typical properties only; current vendor confirmation needed for test basis/specification.",
        "Density is not explicitly labelled true density or accompanied by measurement method."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "trelleborg:sid-350z",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "reported_density_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "density_basis": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "density_tolerance_g_cm3": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "particle_size_statistic": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "particle_size_um": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "pressure_psi": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "pressure_property": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Typical properties table, SID-350Z row"
        },
        "survival_percent": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-350Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "survival_basis": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-350Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "test_method": {
          "source_ids": [
            "ecco_2017"
          ],
          "locator": "p.2, SID-350Z row and ASTM D3102-78 footnote; historical method, current web footnote absent"
        },
        "pressure_mpa": {
          "source_ids": [
            "ecco_web"
          ],
          "locator": "Converted from pressure_psi using pressure_conversion.psi_to_mpa; rounded to 6 decimals"
        }
      },
      "evidence_status": "published_supplier_page"
    },
    {
      "manufacturer": "Potters Industries",
      "family": "Q-CEL",
      "grade": null,
      "particle_class": "hollow_glass_microsphere",
      "record_level": "family_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "potters_web"
      ],
      "source_url": "https://www.pottersindustries.com/micro-glass-beads/",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "current_family_confirmed_grade_properties_missing",
      "uncertainties": [
        "Official family page is not a grade datasheet; numerical grade values withheld.",
        "Current grade-specific specification requested before quantitative ingestion."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "potters:q-cel",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "family_only"
    },
    {
      "manufacturer": "Potters Industries",
      "family": "SPHERICEL",
      "grade": null,
      "particle_class": "hollow_glass_microsphere",
      "record_level": "family_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "potters_web"
      ],
      "source_url": "https://www.pottersindustries.com/micro-glass-beads/",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "current_family_confirmed_grade_properties_missing",
      "uncertainties": [
        "Official family page is not a grade datasheet; numerical grade values withheld.",
        "Current grade-specific specification requested before quantitative ingestion."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "family_range_only": {
        "reported_density_g_cm3_min": 0.25,
        "reported_density_g_cm3_max": 1.1,
        "reported_max_crush_psi": 10000,
        "warning": "Family range only; do not pair endpoints as one material or infer survival basis."
      },
      "id": "potters:sphericel",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {
        "family_range_only": {
          "source_ids": [
            "potters_web"
          ],
          "locator": "SPHERICEL family description; independent range endpoints, no grade-level pairing"
        }
      },
      "evidence_status": "family_only"
    },
    {
      "manufacturer": "Potters Industries",
      "family": "SPHERIGLASS",
      "grade": null,
      "particle_class": "solid_glass_microsphere",
      "record_level": "family_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "potters_web"
      ],
      "source_url": "https://www.pottersindustries.com/micro-glass-beads/",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "current_family_confirmed_grade_properties_missing",
      "uncertainties": [
        "Official family page is not a grade datasheet; numerical grade values withheld.",
        "Solid SPHERIGLASS must not enter the hollow-particle syntactic-buoyancy model as an interchangeable grade."
      ],
      "alternate_observations": [],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "potters:spheriglass",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": false,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "family_only"
    },
    {
      "manufacturer": "Potters Industries",
      "family": "SPHERICEL",
      "grade": "110P8",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "grade_reference",
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_ids": [
        "potters_japan",
        "potters_sphericel_2012"
      ],
      "source_url": "https://www.pqj.co.jp/en/%E4%B8%AD%E7%A9%BA%E3%82%AC%E3%83%A9%E3%82%B9%E3%83%93%E3%83%BC%E3%82%BA",
      "source_date": null,
      "access_date": "2026-10-10",
      "verification_status": "current_grade_identity_historical_properties_only",
      "uncertainties": [
        "Current Japan manufacturer page confirms 110P8 identity, but offers no numerical TDS.",
        "Historical 2012 manufacturer-authored sheet is distributor-hosted; main numerical fields withheld pending current manufacturer TDS.",
        "Other historical SPHERICEL grades not promoted to current records without current official grade evidence."
      ],
      "alternate_observations": [
        {
          "source_id": "potters_sphericel_2012",
          "source_date": "2012",
          "true_density_g_cm3": 1.1,
          "density_tolerance_g_cm3": 0.05,
          "density_method": "Gas displacement pycnometer ASTM D2840",
          "bulk_density_g_cm3": 0.49,
          "particle_size_statistic": "D50 by volume, laser light scatter",
          "particle_size_um": 10,
          "d10_um": 5,
          "d90_um": 21,
          "d97_um": 25,
          "pressure_psi": 10000,
          "pressure_mpa": 68.947573,
          "pressure_property": "suggested maximum working pressure",
          "survival_percent": 90,
          "survival_basis": "by volume",
          "test_method": "isostatic inert gas pressure",
          "access_date": "2026-10-10"
        }
      ],
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "id": "potters:110p8",
      "model_status": "reference_only",
      "model_grade_id": null,
      "review_required": true,
      "literature_links": [],
      "surface_treatment": null,
      "lot_id": null,
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "current_identity_historical_properties"
    },
    {
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_url": null,
      "source_date": null,
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "surface_treatment": null,
      "lot_id": null,
      "model_grade_id": null,
      "id": "potters:q-cel-6014",
      "manufacturer": "Potters Industries",
      "family": "Q-CEL",
      "grade": "6014",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "literature_grade_label",
      "source_ids": [
        "local_psp",
        "potters_web",
        "potters_qcel_archival"
      ],
      "access_date": "2026-10-10",
      "verification_status": "literature_label_current_grade_unverified",
      "uncertainties": [
        "Found in stored paper extractions. Current availability, exact grade identity and properties need a current manufacturer TDS.",
        "Literature rows are not automatically model training or independent validation data.",
        "Historical supplier sheet reports effective liquid-displacement density 0.14 g/cm3 and untamped bulk density 0.08 g/cm3; neither is silently promoted to current true particle density."
      ],
      "alternate_observations": [
        {
          "source_id": "potters_qcel_archival",
          "source_date": null,
          "access_date": "2026-10-10",
          "locator": "p.1 typical properties, 6014 column",
          "observation_status": "historical_supplier_reference",
          "reported_density_g_cm3": 0.14,
          "density_basis": "Effective density by liquid displacement; not labelled true density",
          "bulk_density_g_cm3": 0.08,
          "bulk_density_basis": "Untamped",
          "particle_size_um": 85,
          "particle_size_statistic": "Mean; weighting not stated",
          "particle_size_min_um": 5,
          "particle_size_max_um": 200,
          "note": "Main fields remain unknown pending a current manufacturer grade specification; no pressure or survival value reported."
        }
      ],
      "model_status": "reference_only",
      "review_required": true,
      "literature_links": [
        {
          "paper_id": "W1974839170",
          "stored_rows": 4
        },
        {
          "paper_id": "W2728148627",
          "stored_rows": 24
        }
      ],
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "unresolved_identity"
    },
    {
      "true_density_g_cm3": null,
      "reported_density_g_cm3": null,
      "density_basis": null,
      "density_tolerance_g_cm3": null,
      "particle_size_statistic": null,
      "particle_size_um": null,
      "pressure_psi": null,
      "pressure_mpa": null,
      "pressure_property": null,
      "survival_percent": null,
      "survival_basis": null,
      "test_method": null,
      "source_url": null,
      "source_date": null,
      "youngs_modulus_gpa": null,
      "poisson_ratio": null,
      "foam_strength_mpa": null,
      "qualified_depth_m": null,
      "surface_treatment": null,
      "lot_id": null,
      "model_grade_id": null,
      "id": "potters:q-cel-5020",
      "manufacturer": "Potters Industries",
      "family": "Q-CEL",
      "grade": "5020",
      "particle_class": "hollow_glass_microsphere",
      "record_level": "literature_grade_label",
      "source_ids": [
        "local_psp",
        "potters_web"
      ],
      "access_date": "2026-10-10",
      "verification_status": "literature_label_current_grade_unverified",
      "uncertainties": [
        "Found in stored paper extractions. Current availability, exact grade identity and properties need a current manufacturer TDS.",
        "Literature rows are not automatically model training or independent validation data."
      ],
      "alternate_observations": [],
      "model_status": "reference_only",
      "review_required": true,
      "literature_links": [
        {
          "paper_id": "W2766120207",
          "stored_rows": 10
        }
      ],
      "reviewed_at": "2026-10-10",
      "field_provenance": {},
      "evidence_status": "unresolved_identity"
    }
  ],
  "required_followups": [
    "Obtain current Potters grade-level TDS for Q-CEL 6014/5020 and SPHERICEL grades, including density method, size distribution, surface treatment and pressure/survival protocol.",
    "Resolve Trelleborg SI-160 and SI-200 density discrepancies and SID-106Z / SID-160Z identity.",
    "Confirm which 3M specification revision applies to S38HS, S60HS and iM30K particle-size values; older UK QCM 193.0 and 2019 overview QCM 193.2 values differ.",
    "Resolve original 3M S60 and bare H50 model/literature identities before changing any model parameters.",
    "Obtain partner recipe/process ranges and independent batch outcomes before expanding model support."
  ],
  "model_catalogue_sha256": "40c338ba27e16ccc737cf069e4ac0866145fba7d0c59b44893f99b15ebd96ef6",
  "unresolved_literature": [
    {
      "label": "Eccospheres (OCR: 'Eccospheres-SI grace of Electroni Co., Belgium')",
      "paper_id": "W1486780314",
      "stored_rows": 5,
      "mapped_supplier_grade_id": null,
      "reason": "Historical supplier and precise grade unresolved; not evidence for any current Eccospheres grade."
    }
  ],
  "reviewed_at": "2026-10-10",
  "review_scope": "Source content and identity review. Access/review dates do not establish current availability, lot specifications or model validation. Historical and conflicting observations remain separate."
}
